9H-fluorene-2-carboxaldehyde

Allison J. Amonette; Roger E. Gerkin

doi:10.1107/S0108270198009056

9H-fluorene-2-carboxaldehyde

Allison J. Amonette, Roger E. Gerkin

Biochemistry, Chemistry & Physics

Ohio State University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, C14H10O, crystallized in the centrosymmetric space group P 21/ c with a single molecule in the asymmetric unit. The C-HO interaction having the shortest CO distance involves the ring-bridging atom C9 and one of its H atoms and results in the formation of a cyclic dimer about a center of symmetry. The molecular core is nearly planar. The dihedral angle between the best-fit plane of the ring to which the aldehyde group is attached and the plane of the aldehyde group is 4.4 (9)°. In a number of respects the molecular disposition is similar to that previously determined for the geometrically similar dibenzofuran-4-carboxaldehyde molecule.

Original language	English
Pages (from-to)	1890-1892
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	12
DOIs	https://doi.org/10.1107/S0108270198009056
State	Published - Dec 15 1998

Scopus Subject Areas

General Biochemistry, Genetics and Molecular Biology

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title = "9H-fluorene-2-carboxaldehyde",

abstract = " The title compound, C14H10O, crystallized in the centrosymmetric space group P 21/ c with a single molecule in the asymmetric unit. The C-HO interaction having the shortest CO distance involves the ring-bridging atom C9 and one of its H atoms and results in the formation of a cyclic dimer about a center of symmetry. The molecular core is nearly planar. The dihedral angle between the best-fit plane of the ring to which the aldehyde group is attached and the plane of the aldehyde group is 4.4 (9)°. In a number of respects the molecular disposition is similar to that previously determined for the geometrically similar dibenzofuran-4-carboxaldehyde molecule.",

author = "Amonette, \{Allison J.\} and Gerkin, \{Roger E.\}",

year = "1998",

month = dec,

day = "15",

doi = "10.1107/S0108270198009056",

language = "English",

volume = "54",

pages = "1890--1892",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

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TY - JOUR

T1 - 9H-fluorene-2-carboxaldehyde

AU - Amonette, Allison J.

AU - Gerkin, Roger E.

PY - 1998/12/15

Y1 - 1998/12/15

N2 - The title compound, C14H10O, crystallized in the centrosymmetric space group P 21/ c with a single molecule in the asymmetric unit. The C-HO interaction having the shortest CO distance involves the ring-bridging atom C9 and one of its H atoms and results in the formation of a cyclic dimer about a center of symmetry. The molecular core is nearly planar. The dihedral angle between the best-fit plane of the ring to which the aldehyde group is attached and the plane of the aldehyde group is 4.4 (9)°. In a number of respects the molecular disposition is similar to that previously determined for the geometrically similar dibenzofuran-4-carboxaldehyde molecule.

AB - The title compound, C14H10O, crystallized in the centrosymmetric space group P 21/ c with a single molecule in the asymmetric unit. The C-HO interaction having the shortest CO distance involves the ring-bridging atom C9 and one of its H atoms and results in the formation of a cyclic dimer about a center of symmetry. The molecular core is nearly planar. The dihedral angle between the best-fit plane of the ring to which the aldehyde group is attached and the plane of the aldehyde group is 4.4 (9)°. In a number of respects the molecular disposition is similar to that previously determined for the geometrically similar dibenzofuran-4-carboxaldehyde molecule.

UR - https://www.scopus.com/pages/publications/3242845687

U2 - 10.1107/S0108270198009056

DO - 10.1107/S0108270198009056

M3 - Article

SN - 0108-2701

VL - 54

SP - 1890

EP - 1892

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

9H-fluorene-2-carboxaldehyde

Abstract

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