A neutral Ga6 octahedron: Synthesis, structure, and aromaticity

Brandon Quillian; Pingrong Wei; Chaitanya S. Wannere; Paul V.R. Schleyer; Gregory H. Robinson

doi:10.1021/ja809945v

A neutral Ga₆ octahedron: Synthesis, structure, and aromaticity

Brandon Quillian, Pingrong Wei, Chaitanya S. Wannere, Paul V.R. Schleyer, Gregory H. Robinson

Biochemistry, Chemistry & Physics

University of Georgia

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

Potassium graphite reduction of L:Ga(Mes)Cl₂ [L: =:C{(i-Pr)NC(Me)}₂, Mes = 2,4,6-Me₃C₆H ₂] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl) (Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga₆ octahedron L:Ga[Ga₄Mes₄]Ga:L (3).

Original language	English
Pages (from-to)	3168-3169
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	9
DOIs	https://doi.org/10.1021/ja809945v
State	Published - Mar 11 2009

Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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@article{db8d7eb9645d4a3f99d8cce8a28529c4,

title = "A neutral Ga6 octahedron: Synthesis, structure, and aromaticity",

abstract = "Potassium graphite reduction of L:Ga(Mes)Cl2 [L: =:C\{(i-Pr)NC(Me)\}2, Mes = 2,4,6-Me3C6H 2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl) (Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga6 octahedron L:Ga[Ga4Mes4]Ga:L (3).",

author = "Brandon Quillian and Pingrong Wei and Wannere, \{Chaitanya S.\} and Schleyer, \{Paul V.R.\} and Robinson, \{Gregory H.\}",

year = "2009",

month = mar,

day = "11",

doi = "10.1021/ja809945v",

language = "English",

volume = "131",

pages = "3168--3169",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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TY - JOUR

T1 - A neutral Ga6 octahedron

T2 - Synthesis, structure, and aromaticity

AU - Quillian, Brandon

AU - Wei, Pingrong

AU - Wannere, Chaitanya S.

AU - Schleyer, Paul V.R.

AU - Robinson, Gregory H.

PY - 2009/3/11

Y1 - 2009/3/11

N2 - Potassium graphite reduction of L:Ga(Mes)Cl2 [L: =:C{(i-Pr)NC(Me)}2, Mes = 2,4,6-Me3C6H 2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl) (Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga6 octahedron L:Ga[Ga4Mes4]Ga:L (3).

AB - Potassium graphite reduction of L:Ga(Mes)Cl2 [L: =:C{(i-Pr)NC(Me)}2, Mes = 2,4,6-Me3C6H 2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl) (Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga6 octahedron L:Ga[Ga4Mes4]Ga:L (3).

UR - https://www.scopus.com/pages/publications/68049104703

U2 - 10.1021/ja809945v

DO - 10.1021/ja809945v

M3 - Article

AN - SCOPUS:68049104703

SN - 0002-7863

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SP - 3168

EP - 3169

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 9

ER -

A neutral Ga₆ octahedron: Synthesis, structure, and aromaticity

Abstract

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