A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Z. O. Oyman; W. Ming; F. Micciché; E. Oostveen; J. Van Haveren; R. Van Der Linde

doi:10.1016/j.polymer.2004.08.052

A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Z. O. Oyman, W. Ming, F. Micciché, E. Oostveen, J. Van Haveren, R. Van Der Linde

Biochemistry, Chemistry, & Physics

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7- triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

Original language	English
Pages (from-to)	7431-7436
Number of pages	6
Journal	Polymer
Volume	45
Issue number	22
DOIs	https://doi.org/10.1016/j.polymer.2004.08.052
State	Published - Oct 13 2004

Keywords

Polymer chemistry
Polymer materials

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10.1016/j.polymer.2004.08.052

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title = "A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings",

abstract = "A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7- triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.",

keywords = "Polymer chemistry, Polymer materials",

author = "Oyman, {Z. O.} and W. Ming and F. Miccich{\'e} and E. Oostveen and {Van Haveren}, J. and {Van Der Linde}, R.",

year = "2004",

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doi = "10.1016/j.polymer.2004.08.052",

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T1 - A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

AU - Oyman, Z. O.

AU - Ming, W.

AU - Micciché, F.

AU - Oostveen, E.

AU - Van Haveren, J.

AU - Van Der Linde, R.

PY - 2004/10/13

Y1 - 2004/10/13

N2 - A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7- triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

AB - A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7- triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

KW - Polymer chemistry

KW - Polymer materials

UR - http://www.scopus.com/inward/record.url?scp=4644308235&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2004.08.052

DO - 10.1016/j.polymer.2004.08.052

M3 - Article

AN - SCOPUS:4644308235

SN - 0032-3861

VL - 45

SP - 7431

EP - 7436

JO - Polymer

JF - Polymer

IS - 22

ER -

A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Abstract

Keywords

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