A trimetallic fulvalene-bridged dizirconocene-gallium complex

Brandon Quillian, Yuzhong Wang, Chaitanya S. Wannere, Pingrong Wei, Paul Von Ragué Schleyer, Gregory H. Robinson

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

(Figure Presented) Star GaZr: The X-ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal-metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr-H-Zr hydride in 1 that was undetected by single-crystal X-ray analysis.

Original languageEnglish
Pages (from-to)1836-1838
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number11
DOIs
StatePublished - 2007

Keywords

  • Bridging ligands
  • Gallium
  • Heterometallic complexes
  • Metal-metal interactions
  • Zirconium

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