A trimetallic fulvalene-bridged dizirconocene-gallium complex

Brandon Quillian; Yuzhong Wang; Chaitanya S. Wannere; Pingrong Wei; Paul Von Ragué Schleyer; Gregory H. Robinson

doi:10.1002/anie.200603469

A trimetallic fulvalene-bridged dizirconocene-gallium complex

Brandon Quillian, Yuzhong Wang, Chaitanya S. Wannere, Pingrong Wei, Paul Von Ragué Schleyer, Gregory H. Robinson

Biochemistry, Chemistry & Physics

University of Georgia

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

(Figure Presented) Star GaZr: The X-ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal-metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr-H-Zr hydride in 1 that was undetected by single-crystal X-ray analysis.

Original language	English
Pages (from-to)	1836-1838
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	11
DOIs	https://doi.org/10.1002/anie.200603469
State	Published - 2007

Scopus Subject Areas

Catalysis
General Chemistry

Keywords

Bridging ligands
Gallium
Heterometallic complexes
Metal-metal interactions
Zirconium

Access to Document

10.1002/anie.200603469

Cite this

@article{76e3169b27ac4ea58b6229c12d9c046c,

title = "A trimetallic fulvalene-bridged dizirconocene-gallium complex",

abstract = "(Figure Presented) Star GaZr: The X-ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal-metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr-H-Zr hydride in 1 that was undetected by single-crystal X-ray analysis.",

keywords = "Bridging ligands, Gallium, Heterometallic complexes, Metal-metal interactions, Zirconium",

author = "Brandon Quillian and Yuzhong Wang and Wannere, \{Chaitanya S.\} and Pingrong Wei and Schleyer, \{Paul Von Ragu{\'e}\} and Robinson, \{Gregory H.\}",

year = "2007",

doi = "10.1002/anie.200603469",

language = "English",

volume = "46",

pages = "1836--1838",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "11",

}

TY - JOUR

T1 - A trimetallic fulvalene-bridged dizirconocene-gallium complex

AU - Quillian, Brandon

AU - Wang, Yuzhong

AU - Wannere, Chaitanya S.

AU - Wei, Pingrong

AU - Schleyer, Paul Von Ragué

AU - Robinson, Gregory H.

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Star GaZr: The X-ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal-metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr-H-Zr hydride in 1 that was undetected by single-crystal X-ray analysis.

AB - (Figure Presented) Star GaZr: The X-ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal-metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr-H-Zr hydride in 1 that was undetected by single-crystal X-ray analysis.

KW - Bridging ligands

KW - Gallium

KW - Heterometallic complexes

KW - Metal-metal interactions

KW - Zirconium

UR - https://www.scopus.com/pages/publications/34250789915

U2 - 10.1002/anie.200603469

DO - 10.1002/anie.200603469

M3 - Article

AN - SCOPUS:34250789915

SN - 1433-7851

VL - 46

SP - 1836

EP - 1838

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

A trimetallic fulvalene-bridged dizirconocene-gallium complex

Abstract

Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this