Determination of the structure of HCl BF3

James M. LoBue; Jane K. Rice; Thomas A. Blake; Stewart E. Novick

doi:10.1063/1.451798

Determination of the structure of HCl BF₃

James M. LoBue, Jane K. Rice, Thomas A. Blake, Stewart E. Novick

Biochemistry, Chemistry & Physics

Research output: Contribution to journal › Article › peer-review

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Abstract

The structure of the weakly bound complex HCl BF₃ has been determined by molecular beam electric resonance spectroscopy. The molecule is a near prolate symmetric top with the chlorine atom 3.17 Å above the boron atom, on or very near the BF₃ threefold axis. The B-Cl-H angle is close to 90°. The spectroscopic constants for the H³⁵Cl ¹¹BF₃ isotope are (B+C)/2=1774.117(4) MHz, D _J=5.6(5) kHz, eqQ_a (³⁵Cl)=+25.761(8) MHz, eqQ^a (¹¹B)=+2.672(25) MHz, and μ_a=0.484(5)D.

Original language	English
Pages (from-to)	4261-4268
Number of pages	8
Journal	Journal of Chemical Physics
Volume	85
Issue number	8
DOIs	https://doi.org/10.1063/1.451798
State	Published - 1986

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General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{14ded306146b4b95af530263291f7b46,

title = "Determination of the structure of HCl BF3",

abstract = "The structure of the weakly bound complex HCl BF3 has been determined by molecular beam electric resonance spectroscopy. The molecule is a near prolate symmetric top with the chlorine atom 3.17 {\AA} above the boron atom, on or very near the BF3 threefold axis. The B-Cl-H angle is close to 90°. The spectroscopic constants for the H35Cl 11BF3 isotope are (B+C)/2=1774.117(4) MHz, D J=5.6(5) kHz, eqQa (35Cl)=+25.761(8) MHz, eqQa (11B)=+2.672(25) MHz, and μa=0.484(5)D.",

author = "LoBue, \{James M.\} and Rice, \{Jane K.\} and Blake, \{Thomas A.\} and Novick, \{Stewart E.\}",

year = "1986",

doi = "10.1063/1.451798",

language = "English",

volume = "85",

pages = "4261--4268",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "8",

}

TY - JOUR

T1 - Determination of the structure of HCl BF3

AU - LoBue, James M.

AU - Rice, Jane K.

AU - Blake, Thomas A.

AU - Novick, Stewart E.

PY - 1986

Y1 - 1986

N2 - The structure of the weakly bound complex HCl BF3 has been determined by molecular beam electric resonance spectroscopy. The molecule is a near prolate symmetric top with the chlorine atom 3.17 Å above the boron atom, on or very near the BF3 threefold axis. The B-Cl-H angle is close to 90°. The spectroscopic constants for the H35Cl 11BF3 isotope are (B+C)/2=1774.117(4) MHz, D J=5.6(5) kHz, eqQa (35Cl)=+25.761(8) MHz, eqQa (11B)=+2.672(25) MHz, and μa=0.484(5)D.

AB - The structure of the weakly bound complex HCl BF3 has been determined by molecular beam electric resonance spectroscopy. The molecule is a near prolate symmetric top with the chlorine atom 3.17 Å above the boron atom, on or very near the BF3 threefold axis. The B-Cl-H angle is close to 90°. The spectroscopic constants for the H35Cl 11BF3 isotope are (B+C)/2=1774.117(4) MHz, D J=5.6(5) kHz, eqQa (35Cl)=+25.761(8) MHz, eqQa (11B)=+2.672(25) MHz, and μa=0.484(5)D.

UR - https://www.scopus.com/pages/publications/0000038050

U2 - 10.1063/1.451798

DO - 10.1063/1.451798

M3 - Article

AN - SCOPUS:0000038050

SN - 0021-9606

VL - 85

SP - 4261

EP - 4268

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

ER -

Determination of the structure of HCl BF₃

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