Energy transfer to Gd3+ from the self-trapped exciton in ScPO4:Gd3+ — In the case of persistent luminescence

Chengrui Wang; Feng Liu; Xiao jun Wang

doi:10.1016/j.jlumin.2022.119511

Energy transfer to Gd³⁺ from the self-trapped exciton in ScPO₄:Gd³⁺ — In the case of persistent luminescence

Chengrui Wang, Feng Liu, Xiao jun Wang

Biochemistry, Chemistry, & Physics

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We report a persistent luminescence phenomenon of ScPO₄:Gd³⁺ phosphor, which exhibits long-lasting ultraviolet emission peaking at 313 nm after the end of X-ray irradiation. Unlike the steady-state luminescence of the phosphor excited by ionizing irradiation, no quantum-cutting emission is involved in the persistent luminescence. We ascribe the presence of persistent luminescence, as well as the absence of quantum cutting, to the effect of self-trapped exciton on the electron and energy transfers. This work provides some insights to the understanding of Gd³⁺-activated ultraviolet persistent luminescence.

Original language	English
Article number	119511
Journal	Journal of Luminescence
Volume	254
DOIs	https://doi.org/10.1016/j.jlumin.2022.119511
State	Published - Feb 2023

Keywords

Gd
Quantum cutting
Self-trapped exciton
Ultraviolet persistent luminescence

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10.1016/j.jlumin.2022.119511

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title = "Energy transfer to Gd3+ from the self-trapped exciton in ScPO4:Gd3+ — In the case of persistent luminescence",

abstract = "We report a persistent luminescence phenomenon of ScPO4:Gd3+ phosphor, which exhibits long-lasting ultraviolet emission peaking at 313 nm after the end of X-ray irradiation. Unlike the steady-state luminescence of the phosphor excited by ionizing irradiation, no quantum-cutting emission is involved in the persistent luminescence. We ascribe the presence of persistent luminescence, as well as the absence of quantum cutting, to the effect of self-trapped exciton on the electron and energy transfers. This work provides some insights to the understanding of Gd3+-activated ultraviolet persistent luminescence.",

keywords = "Gd, Quantum cutting, Self-trapped exciton, Ultraviolet persistent luminescence",

author = "Chengrui Wang and Feng Liu and Wang, {Xiao jun}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

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doi = "10.1016/j.jlumin.2022.119511",

language = "English",

volume = "254",

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TY - JOUR

T1 - Energy transfer to Gd3+ from the self-trapped exciton in ScPO4:Gd3+ — In the case of persistent luminescence

AU - Wang, Chengrui

AU - Liu, Feng

AU - Wang, Xiao jun

PY - 2023/2

Y1 - 2023/2

N2 - We report a persistent luminescence phenomenon of ScPO4:Gd3+ phosphor, which exhibits long-lasting ultraviolet emission peaking at 313 nm after the end of X-ray irradiation. Unlike the steady-state luminescence of the phosphor excited by ionizing irradiation, no quantum-cutting emission is involved in the persistent luminescence. We ascribe the presence of persistent luminescence, as well as the absence of quantum cutting, to the effect of self-trapped exciton on the electron and energy transfers. This work provides some insights to the understanding of Gd3+-activated ultraviolet persistent luminescence.

AB - We report a persistent luminescence phenomenon of ScPO4:Gd3+ phosphor, which exhibits long-lasting ultraviolet emission peaking at 313 nm after the end of X-ray irradiation. Unlike the steady-state luminescence of the phosphor excited by ionizing irradiation, no quantum-cutting emission is involved in the persistent luminescence. We ascribe the presence of persistent luminescence, as well as the absence of quantum cutting, to the effect of self-trapped exciton on the electron and energy transfers. This work provides some insights to the understanding of Gd3+-activated ultraviolet persistent luminescence.

KW - Gd

KW - Quantum cutting

KW - Self-trapped exciton

KW - Ultraviolet persistent luminescence

UR - http://www.scopus.com/inward/record.url?scp=85142197402&partnerID=8YFLogxK

U2 - 10.1016/j.jlumin.2022.119511

DO - 10.1016/j.jlumin.2022.119511

M3 - Article

AN - SCOPUS:85142197402

SN - 0022-2313

VL - 254

JO - Journal of Luminescence

JF - Journal of Luminescence

M1 - 119511

ER -

Energy transfer to Gd³⁺ from the self-trapped exciton in ScPO₄:Gd³⁺ — In the case of persistent luminescence

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Keywords

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