TY - JOUR
T1 - Enhanced luminescence performance of CaO:Ce3+,Li+,F- phosphor and its phosphor-in-glass based high-power warm LED properties
AU - Deng, Jiankun
AU - Zhang, Haoran
AU - Zhang, Xuejie
AU - Molokeev, Maxim S.
AU - Qiu, Jianbei
AU - Liu, Yingliang
AU - Lei, Bingfu
AU - Ma, Li
AU - Wang, Xiaojun
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2018.
PY - 2018
Y1 - 2018
N2 - To obtain white light-emitted diodes (wLEDs) with a low correlated color temperature (CCT) and a high color rendering index (CRI), red-emission is indispensable in their emission spectra. Herein, CaO:Ce3+,Li+,F- yellow phosphors with more red spectral component have been prepared via a high temperature solid-state reaction. As compared to the F- undoped samples, CaO:Ce3+,Li+,F- phosphor have lower critical doping concentration of Ce3+ and show stronger luminescence. At the critical concentration, a quantum efficiency of 66.4% and enhanced thermal and chemical stability were obtained in CaO:Ce3+,Li+,F-. Furthermore, a CaO:Ce3+,Li+,F--based phosphor-in-glass (PiG) using the red-emitting glass system with the composition of SiO2-Na2CO3-Al2O3-CaO:Eu3+ as the host material was constructed and used for high-power white LED applications. Such PiG samples with different phosphor doping concentrations can satisfy various light color demands and display higher reliability than the CaO:Ce3+,Li+,F- phosphor. An optimal PiG-based wLED exhibits color coordinates of (0.3769, 0.3386), a CCT of 3774 K, a CRI of 82.5 and a LE of 73.1 when the mass ratio of phosphor to glass matrix was 7:50 in PiG. Moreover, such PiG-based wLED also showed acceptable color stability under different drive currents. All the above results demonstrate that CaO:Ce3+,Li+,F- can be expected to be a potential alternative yellow phosphor for blue light excited PiG based warm wLEDs, particularly for high-power devices.
AB - To obtain white light-emitted diodes (wLEDs) with a low correlated color temperature (CCT) and a high color rendering index (CRI), red-emission is indispensable in their emission spectra. Herein, CaO:Ce3+,Li+,F- yellow phosphors with more red spectral component have been prepared via a high temperature solid-state reaction. As compared to the F- undoped samples, CaO:Ce3+,Li+,F- phosphor have lower critical doping concentration of Ce3+ and show stronger luminescence. At the critical concentration, a quantum efficiency of 66.4% and enhanced thermal and chemical stability were obtained in CaO:Ce3+,Li+,F-. Furthermore, a CaO:Ce3+,Li+,F--based phosphor-in-glass (PiG) using the red-emitting glass system with the composition of SiO2-Na2CO3-Al2O3-CaO:Eu3+ as the host material was constructed and used for high-power white LED applications. Such PiG samples with different phosphor doping concentrations can satisfy various light color demands and display higher reliability than the CaO:Ce3+,Li+,F- phosphor. An optimal PiG-based wLED exhibits color coordinates of (0.3769, 0.3386), a CCT of 3774 K, a CRI of 82.5 and a LE of 73.1 when the mass ratio of phosphor to glass matrix was 7:50 in PiG. Moreover, such PiG-based wLED also showed acceptable color stability under different drive currents. All the above results demonstrate that CaO:Ce3+,Li+,F- can be expected to be a potential alternative yellow phosphor for blue light excited PiG based warm wLEDs, particularly for high-power devices.
UR - http://www.scopus.com/inward/record.url?scp=85045856133&partnerID=8YFLogxK
U2 - 10.1039/c8tc00813b
DO - 10.1039/c8tc00813b
M3 - Article
AN - SCOPUS:85045856133
SN - 2050-7534
VL - 6
SP - 4077
EP - 4086
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
IS - 15
ER -