Enhancement of the red emission in CaTiO3:Pr3+ by addition of rare earth oxides

Xianmin Zhang; Jiahua Zhang; Xia Zhang; Li Chen; Yongshi Luo; Xiao jun Wang

doi:10.1016/j.cplett.2006.12.023

Enhancement of the red emission in CaTiO₃:Pr³⁺ by addition of rare earth oxides

Xianmin Zhang
, Jiahua Zhang
, Xia Zhang
, Li Chen
, Yongshi Luo
, Xiao jun Wang

Biochemistry, Chemistry & Physics

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

Enhancement of the ¹D₂-³H₄ red emission of CaTiO₃:Pr³⁺ with addition of rare earth oxides Ln₂O₃ (Ln = Lu, La, Gd) is reported. Ca²⁺ and Ti⁴⁺ in CaTiO₃ can be substituted by Ln³⁺ ions as donors and acceptors, respectively. Ca²⁺ and Ti⁴⁺ vacancies, as quenching centers in the host, are effectively suppressed by the self-compensation, leading to the increase of lifetimes and then the emission efficiency of ¹D₂. The red fluorescence intensity for CaTiO₃:Pr³⁺ phosphor co-doped with 5 mol% Lu₂O₃ is nearly 3 times greater than that of the Lu-free samples.

Original language	English
Pages (from-to)	237-240
Number of pages	4
Journal	Chemical Physics Letters
Volume	434
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2006.12.023
State	Published - Feb 5 2007

Scopus Subject Areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.cplett.2006.12.023

Cite this

@article{68c6cc2d4a32449fb061698efe75b33b,

title = "Enhancement of the red emission in CaTiO3:Pr3+ by addition of rare earth oxides",

abstract = "Enhancement of the 1D2-3H4 red emission of CaTiO3:Pr3+ with addition of rare earth oxides Ln2O3 (Ln = Lu, La, Gd) is reported. Ca2+ and Ti4+ in CaTiO3 can be substituted by Ln3+ ions as donors and acceptors, respectively. Ca2+ and Ti4+ vacancies, as quenching centers in the host, are effectively suppressed by the self-compensation, leading to the increase of lifetimes and then the emission efficiency of 1D2. The red fluorescence intensity for CaTiO3:Pr3+ phosphor co-doped with 5 mol\% Lu2O3 is nearly 3 times greater than that of the Lu-free samples.",

author = "Xianmin Zhang and Jiahua Zhang and Xia Zhang and Li Chen and Yongshi Luo and Wang, \{Xiao jun\}",

year = "2007",

month = feb,

day = "5",

doi = "10.1016/j.cplett.2006.12.023",

language = "English",

volume = "434",

pages = "237--240",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "4-6",

}

TY - JOUR

T1 - Enhancement of the red emission in CaTiO3:Pr3+ by addition of rare earth oxides

AU - Zhang, Xianmin

AU - Zhang, Jiahua

AU - Zhang, Xia

AU - Chen, Li

AU - Luo, Yongshi

AU - Wang, Xiao jun

PY - 2007/2/5

Y1 - 2007/2/5

N2 - Enhancement of the 1D2-3H4 red emission of CaTiO3:Pr3+ with addition of rare earth oxides Ln2O3 (Ln = Lu, La, Gd) is reported. Ca2+ and Ti4+ in CaTiO3 can be substituted by Ln3+ ions as donors and acceptors, respectively. Ca2+ and Ti4+ vacancies, as quenching centers in the host, are effectively suppressed by the self-compensation, leading to the increase of lifetimes and then the emission efficiency of 1D2. The red fluorescence intensity for CaTiO3:Pr3+ phosphor co-doped with 5 mol% Lu2O3 is nearly 3 times greater than that of the Lu-free samples.

AB - Enhancement of the 1D2-3H4 red emission of CaTiO3:Pr3+ with addition of rare earth oxides Ln2O3 (Ln = Lu, La, Gd) is reported. Ca2+ and Ti4+ in CaTiO3 can be substituted by Ln3+ ions as donors and acceptors, respectively. Ca2+ and Ti4+ vacancies, as quenching centers in the host, are effectively suppressed by the self-compensation, leading to the increase of lifetimes and then the emission efficiency of 1D2. The red fluorescence intensity for CaTiO3:Pr3+ phosphor co-doped with 5 mol% Lu2O3 is nearly 3 times greater than that of the Lu-free samples.

UR - https://www.scopus.com/pages/publications/33846197921

U2 - 10.1016/j.cplett.2006.12.023

DO - 10.1016/j.cplett.2006.12.023

M3 - Article

AN - SCOPUS:33846197921

SN - 0009-2614

VL - 434

SP - 237

EP - 240

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Enhancement of the red emission in CaTiO₃:Pr³⁺ by addition of rare earth oxides

Abstract

Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this