Gallepins. Neutral gallium analogues of the tropylium ion: Synthesis, structure, and aromaticity

Brandon Quillian; Yuzhong Wang; Pingrong Wei; Chaitanya S. Wannere; Paul V.R. Schleyer; Gregory H. Robinson

doi:10.1021/ja075428d

Gallepins. Neutral gallium analogues of the tropylium ion: Synthesis, structure, and aromaticity

Brandon Quillian
, Yuzhong Wang
, Pingrong Wei
, Chaitanya S. Wannere
, Paul V.R. Schleyer
, Gregory H. Robinson

Biochemistry, Chemistry & Physics

University of Georgia

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The synthesis of the first gallepin derivative, the neutral gallium-based analogue of the tropylium ion, is described. The title compound, containing two gallepin moieties linked by a TMEDA unit, was characterized by ¹H NMR, elemental analyses, and single-crystal X-ray diffraction. In addition, computations provide insight into the nature of the bonding and aromaticity of this novel compound.

Original language	English
Pages (from-to)	13380-13381
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	44
DOIs	https://doi.org/10.1021/ja075428d
State	Published - Nov 7 2007

Scopus Subject Areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja075428d

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abstract = "The synthesis of the first gallepin derivative, the neutral gallium-based analogue of the tropylium ion, is described. The title compound, containing two gallepin moieties linked by a TMEDA unit, was characterized by 1H NMR, elemental analyses, and single-crystal X-ray diffraction. In addition, computations provide insight into the nature of the bonding and aromaticity of this novel compound.",

author = "Brandon Quillian and Yuzhong Wang and Pingrong Wei and Wannere, \{Chaitanya S.\} and Schleyer, \{Paul V.R.\} and Robinson, \{Gregory H.\}",

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T2 - Synthesis, structure, and aromaticity

AU - Quillian, Brandon

AU - Wang, Yuzhong

AU - Wei, Pingrong

AU - Wannere, Chaitanya S.

AU - Schleyer, Paul V.R.

AU - Robinson, Gregory H.

PY - 2007/11/7

Y1 - 2007/11/7

N2 - The synthesis of the first gallepin derivative, the neutral gallium-based analogue of the tropylium ion, is described. The title compound, containing two gallepin moieties linked by a TMEDA unit, was characterized by 1H NMR, elemental analyses, and single-crystal X-ray diffraction. In addition, computations provide insight into the nature of the bonding and aromaticity of this novel compound.

AB - The synthesis of the first gallepin derivative, the neutral gallium-based analogue of the tropylium ion, is described. The title compound, containing two gallepin moieties linked by a TMEDA unit, was characterized by 1H NMR, elemental analyses, and single-crystal X-ray diffraction. In addition, computations provide insight into the nature of the bonding and aromaticity of this novel compound.

UR - https://www.scopus.com/pages/publications/35948959692

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JF - Journal of the American Chemical Society

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ER -

Gallepins. Neutral gallium analogues of the tropylium ion: Synthesis, structure, and aromaticity

Abstract

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