Heteroatoms tri-doped carbon hollow spheres as the anode material of sodium ion battery

Xiaowei Zhao; Yue Zhang; Tingting Liu; Mingjun Xiao; Baiting Du; Xi Lu; Fuliang Zhu; Yanshuang Meng

doi:10.1016/j.jelechem.2023.117553

Heteroatoms tri-doped carbon hollow spheres as the anode material of sodium ion battery

Xiaowei Zhao
, Yue Zhang
, Tingting Liu
, Mingjun Xiao
, Baiting Du
, Xi Lu
, Fuliang Zhu
, Yanshuang Meng

Manufacturing Engineering

Lanzhou University of Technology
Georgia Southern University
State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

B, F and N tri-doped carbon hollow spheres (BFNHCS) were prepared by a simple polymerization method, using polydopamine (PDA) as C and N sources and ionic liquid 1-butyl-3-methylimidazole tetrafluoroborate as B and F sources. The BFNHCS has large electrode/electrolyte interface, large interlayer spacing and good conductivity due to the heteroatoms doping and hollow structure. When using BFNHCS as the anode material for sodium ion batteries, it shows specific capacity of 255.6, 231.5, 197.4, 178.2, 157.8, 134.5 and 116.4 mAh g⁻¹ at 0.1, 0.2, 0.5, 1.0, 2.0, 5.0 and 10.0 A g⁻¹, respectively. It also exhibits an excellent sodium-storage capacity of 136.5 mAh g⁻¹ after 1000 cycles at 5.0 A g⁻¹.

Original language	English
Article number	117553
Journal	Journal of Electroanalytical Chemistry
Volume	941
DOIs	https://doi.org/10.1016/j.jelechem.2023.117553
State	Published - May 16 2023

Scopus Subject Areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

Keywords

Carbon hollow sphere
Heteroatoms tri-doping
Sodium ion battery

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10.1016/j.jelechem.2023.117553

Cite this

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title = "Heteroatoms tri-doped carbon hollow spheres as the anode material of sodium ion battery",

abstract = "B, F and N tri-doped carbon hollow spheres (BFNHCS) were prepared by a simple polymerization method, using polydopamine (PDA) as C and N sources and ionic liquid 1-butyl-3-methylimidazole tetrafluoroborate as B and F sources. The BFNHCS has large electrode/electrolyte interface, large interlayer spacing and good conductivity due to the heteroatoms doping and hollow structure. When using BFNHCS as the anode material for sodium ion batteries, it shows specific capacity of 255.6, 231.5, 197.4, 178.2, 157.8, 134.5 and 116.4 mAh g−1 at 0.1, 0.2, 0.5, 1.0, 2.0, 5.0 and 10.0 A g−1, respectively. It also exhibits an excellent sodium-storage capacity of 136.5 mAh g−1 after 1000 cycles at 5.0 A g−1.",

keywords = "Carbon hollow sphere, Heteroatoms tri-doping, Sodium ion battery",

author = "Xiaowei Zhao and Yue Zhang and Tingting Liu and Mingjun Xiao and Baiting Du and Xi Lu and Fuliang Zhu and Yanshuang Meng",

note = "Publisher Copyright: {\textcopyright} 2023",

year = "2023",

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day = "16",

doi = "10.1016/j.jelechem.2023.117553",

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TY - JOUR

T1 - Heteroatoms tri-doped carbon hollow spheres as the anode material of sodium ion battery

AU - Zhao, Xiaowei

AU - Zhang, Yue

AU - Liu, Tingting

AU - Xiao, Mingjun

AU - Du, Baiting

AU - Lu, Xi

AU - Zhu, Fuliang

AU - Meng, Yanshuang

PY - 2023/5/16

Y1 - 2023/5/16

N2 - B, F and N tri-doped carbon hollow spheres (BFNHCS) were prepared by a simple polymerization method, using polydopamine (PDA) as C and N sources and ionic liquid 1-butyl-3-methylimidazole tetrafluoroborate as B and F sources. The BFNHCS has large electrode/electrolyte interface, large interlayer spacing and good conductivity due to the heteroatoms doping and hollow structure. When using BFNHCS as the anode material for sodium ion batteries, it shows specific capacity of 255.6, 231.5, 197.4, 178.2, 157.8, 134.5 and 116.4 mAh g−1 at 0.1, 0.2, 0.5, 1.0, 2.0, 5.0 and 10.0 A g−1, respectively. It also exhibits an excellent sodium-storage capacity of 136.5 mAh g−1 after 1000 cycles at 5.0 A g−1.

AB - B, F and N tri-doped carbon hollow spheres (BFNHCS) were prepared by a simple polymerization method, using polydopamine (PDA) as C and N sources and ionic liquid 1-butyl-3-methylimidazole tetrafluoroborate as B and F sources. The BFNHCS has large electrode/electrolyte interface, large interlayer spacing and good conductivity due to the heteroatoms doping and hollow structure. When using BFNHCS as the anode material for sodium ion batteries, it shows specific capacity of 255.6, 231.5, 197.4, 178.2, 157.8, 134.5 and 116.4 mAh g−1 at 0.1, 0.2, 0.5, 1.0, 2.0, 5.0 and 10.0 A g−1, respectively. It also exhibits an excellent sodium-storage capacity of 136.5 mAh g−1 after 1000 cycles at 5.0 A g−1.

KW - Carbon hollow sphere

KW - Heteroatoms tri-doping

KW - Sodium ion battery

UR - https://www.scopus.com/pages/publications/85159431260

U2 - 10.1016/j.jelechem.2023.117553

DO - 10.1016/j.jelechem.2023.117553

M3 - Article

AN - SCOPUS:85159431260

SN - 1572-6657

VL - 941

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

M1 - 117553

ER -

Heteroatoms tri-doped carbon hollow spheres as the anode material of sodium ion battery

Abstract

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Keywords

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