Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

Fabrizio Miccichè; Marion A. Van Straten; Weihua Ming; Eef Oostveen; Jacco Van Haveren; Rob Van Der Linde; Jan Reedijk

doi:10.1016/j.ijms.2005.08.014

Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

Fabrizio Miccichè, Marion A. Van Straten, Weihua Ming, Eef Oostveen, Jacco Van Haveren, Rob Van Der Linde, Jan Reedijk

Biochemistry, Chemistry, & Physics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M₃ up to M₆ as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

Original language	English
Pages (from-to)	80-83
Number of pages	4
Journal	International Journal of Mass Spectrometry
Volume	246
Issue number	1-3
DOIs	https://doi.org/10.1016/j.ijms.2005.08.014
State	Published - Nov 1 2005

Keywords

Driers
ESI-MS
Iron
Metal clusters

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@article{30dd430e18f44b8c815374bb18f8cbe6,

title = "Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)",

abstract = "The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.",

keywords = "Driers, ESI-MS, Iron, Metal clusters",

author = "Fabrizio Miccich{\`e} and {Van Straten}, {Marion A.} and Weihua Ming and Eef Oostveen and {Van Haveren}, Jacco and {Van Der Linde}, Rob and Jan Reedijk",

year = "2005",

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doi = "10.1016/j.ijms.2005.08.014",

language = "English",

volume = "246",

pages = "80--83",

journal = "International Journal of Mass Spectrometry",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

AU - Miccichè, Fabrizio

AU - Van Straten, Marion A.

AU - Ming, Weihua

AU - Oostveen, Eef

AU - Van Haveren, Jacco

AU - Van Der Linde, Rob

AU - Reedijk, Jan

PY - 2005/11/1

Y1 - 2005/11/1

N2 - The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

AB - The oxidative drying of alkyd paints has many similarities with the way lipids are oxidized in biological systems. Metal salts based on Co, Fe and Mn are added to accelerate the oxidative drying of conventional alkyd paints. Although the mechanism by which alkyd paints dry has been the subject of numerous investigations, little information is available on the structure and the actual mechanism by which driers catalyze the oxidation process. In this communication we describe the identification of metal clusters in drier solutions by electrospray ionization mass spectrometry (ESI-MS). Evidence is provided for the presence of several metal clusters ranging from M3 up to M6 as well as the coexistence of mixtures of (mixed-valence) clusters in the same solution.

KW - Driers

KW - ESI-MS

KW - Iron

KW - Metal clusters

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U2 - 10.1016/j.ijms.2005.08.014

DO - 10.1016/j.ijms.2005.08.014

M3 - Article

AN - SCOPUS:26844435789

SN - 1387-3806

VL - 246

SP - 80

EP - 83

JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

IS - 1-3

ER -

Identification of mixed-valence metal clusters in drier solutions for alkyd-based paints by electrospray ionization mass spectrometry (ESI-MS)

Abstract

Keywords

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