Improved rate capability and cycling stability of bicontinuous hierarchical mesoporous LiFePO₄/C microbelts for lithium-ion batteries

Bicontinuous hierarchical mesoporous LiFePO₄/C (BHM-LFP/C) microbelts have been synthesized using a simple dual-solvent electrospinning method for the first time. The use of a dual-solvent is beneficial for the electrospinning synthesis, which increases the salt solubility, as well as decreases the surface tension to improve the spinnability. The sample exhibits a high reversible capacity (153 mA h g^-1 at 0.5C), and achieves an excellent high rate cycling performance. The enhanced electrochemical performance can be attributed to the unique microbelts providing bicontinuous electron/ion pathways, and the thoroughly mesoporous structure facilitating electrolyte penetration, especially for hierarchical architectures, which have three-dimensional diffusion channels for Li⁺. This method can be extended to fabricate other electrospun multi-element oxide cathode materials for advanced lithium-ion batteries.