In Situ Coating on LiFePO 4 with Ionic Liquid as Carbon Source for High-Performance Lithium Batteries

Jun Xia; Fuliang Zhu; Lei Wang; Gongrui Wang; Yanshuang Meng; Yue Zhang

doi:10.1007/s11051-018-4298-z

In Situ Coating on LiFePO 4 with Ionic Liquid as Carbon Source for High-Performance Lithium Batteries

Jun Xia, Fuliang Zhu, Lei Wang, Gongrui Wang, Yanshuang Meng, Yue Zhang

Manufacturing Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

LiFePO₄/C materials were synthesized via an in situ coating on LiFePO₄ with 1-butyl-3-methylimidazolium dicyanamide [BMIm][N(CN)₂] as a carbon source. The electrode materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results revealed that 1–2 nm carbon films were successfully coated on the LiFePO₄ particles. The electrochemical properties of LiFePO₄/C composite were investigated by cyclic voltammetry (CV) curves, electrochemical impedance spectra (EIS), and electrochemical analysis. The test results showed that the LiFePO₄/C composite possessed outstanding reversibility, cycle performance, and rate performance. The discharge capacities of LiFePO₄/C were 161.5 mAh g⁻¹ at 0.1 C and 143.6 mAh g⁻¹ at 1 C, respectively. The excellent electrochemical properties of the LiFePO₄/C electrode were mainly due to the thin, uniform, and highly graphitized carbon films.

Original language	American English
Journal	Journal of Nanoparticle Research
Volume	20
DOIs	https://doi.org/10.1007/s11051-018-4298-z
State	Published - Jul 1 2018

Disciplines

Manufacturing

Keywords

Electrochemistry
Energy storage
In situ coating
Ionic liquid
LiFePO4
Lithium ion batteries

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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@article{2af6eaf618144a4793cf5a19630e6006,

title = "In Situ Coating on LiFePO 4 with Ionic Liquid as Carbon Source for High-Performance Lithium Batteries",

abstract = "LiFePO4/C materials were synthesized via an in situ coating on LiFePO4 with 1-butyl-3-methylimidazolium dicyanamide [BMIm][N(CN)2] as a carbon source. The electrode materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results revealed that 1–2 nm carbon films were successfully coated on the LiFePO4 particles. The electrochemical properties of LiFePO4/C composite were investigated by cyclic voltammetry (CV) curves, electrochemical impedance spectra (EIS), and electrochemical analysis. The test results showed that the LiFePO4/C composite possessed outstanding reversibility, cycle performance, and rate performance. The discharge capacities of LiFePO4/C were 161.5 mAh g−1 at 0.1 C and 143.6 mAh g−1 at 1 C, respectively. The excellent electrochemical properties of the LiFePO4/C electrode were mainly due to the thin, uniform, and highly graphitized carbon films.",

keywords = "Electrochemistry, Energy storage, In situ coating, Ionic liquid, LiFePO4, Lithium ion batteries",

author = "Jun Xia and Fuliang Zhu and Lei Wang and Gongrui Wang and Yanshuang Meng and Yue Zhang",

note = "Publisher Copyright: {\textcopyright} 2018, Springer Nature B.V.",

year = "2018",

month = jul,

day = "1",

doi = "10.1007/s11051-018-4298-z",

language = "American English",

volume = "20",

journal = "Journal of Nanoparticle Research",

issn = "1388-0764",

publisher = "Springer Netherlands",

}

TY - JOUR

T1 - In Situ Coating on LiFePO 4 with Ionic Liquid as Carbon Source for High-Performance Lithium Batteries

AU - Xia, Jun

AU - Zhu, Fuliang

AU - Wang, Lei

AU - Wang, Gongrui

AU - Meng, Yanshuang

AU - Zhang, Yue

PY - 2018/7/1

Y1 - 2018/7/1

N2 - LiFePO4/C materials were synthesized via an in situ coating on LiFePO4 with 1-butyl-3-methylimidazolium dicyanamide [BMIm][N(CN)2] as a carbon source. The electrode materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results revealed that 1–2 nm carbon films were successfully coated on the LiFePO4 particles. The electrochemical properties of LiFePO4/C composite were investigated by cyclic voltammetry (CV) curves, electrochemical impedance spectra (EIS), and electrochemical analysis. The test results showed that the LiFePO4/C composite possessed outstanding reversibility, cycle performance, and rate performance. The discharge capacities of LiFePO4/C were 161.5 mAh g−1 at 0.1 C and 143.6 mAh g−1 at 1 C, respectively. The excellent electrochemical properties of the LiFePO4/C electrode were mainly due to the thin, uniform, and highly graphitized carbon films.

AB - LiFePO4/C materials were synthesized via an in situ coating on LiFePO4 with 1-butyl-3-methylimidazolium dicyanamide [BMIm][N(CN)2] as a carbon source. The electrode materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results revealed that 1–2 nm carbon films were successfully coated on the LiFePO4 particles. The electrochemical properties of LiFePO4/C composite were investigated by cyclic voltammetry (CV) curves, electrochemical impedance spectra (EIS), and electrochemical analysis. The test results showed that the LiFePO4/C composite possessed outstanding reversibility, cycle performance, and rate performance. The discharge capacities of LiFePO4/C were 161.5 mAh g−1 at 0.1 C and 143.6 mAh g−1 at 1 C, respectively. The excellent electrochemical properties of the LiFePO4/C electrode were mainly due to the thin, uniform, and highly graphitized carbon films.

KW - Electrochemistry

KW - Energy storage

KW - In situ coating

KW - Ionic liquid

KW - LiFePO4

KW - Lithium ion batteries

UR - https://digitalcommons.georgiasouthern.edu/manufact-eng-facpubs/89

U2 - 10.1007/s11051-018-4298-z

DO - 10.1007/s11051-018-4298-z

M3 - Article

SN - 1388-0764

VL - 20

JO - Journal of Nanoparticle Research

JF - Journal of Nanoparticle Research

ER -

In Situ Coating on LiFePO 4 with Ionic Liquid as Carbon Source for High-Performance Lithium Batteries

Abstract

Disciplines

Keywords

UN SDGs

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