Abstract
Intensity parametrization of the electric dipole transitions within 4f2 configuration of Pr3+ in SrAl12O19 are reported, in which the mixing of the 4f transitional states with the explicit 4f5d states is taken into account. A new set of phenomenological intensity parameters, Tkq, are put forward, which are obtained from a best fit of the calculated and measured relative intensities of transitions from the 3P0 level to the lower J multiplets. The fitted values, T33 = 3.26 × 10-5 and T53 = -5.46 × l0-5, have been used to analyze the transitions originating from the 1S0 level. The present results are compared with that of the Judd-Ofelt analysis and the experimental measurements.
Original language | English |
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Pages (from-to) | 6020-6024 |
Number of pages | 5 |
Journal | Wuli Xuebao/Acta Physica Sinica |
Volume | 55 |
Issue number | 11 |
State | Published - Nov 2006 |
Keywords
- 4f5d configuration
- Intensity parameter
- Parity mixing
- SrAlO:Pr