Intra- and Intermolecular C-H Interactions in Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

S. Shanmuga Sundara Raj; Hoong-Kun Fun; Ji Wu; Yu-Peng Tian; Fu-Xin Xie; Ze-Huai Shao; Sheng-Li Li

Intra- and Intermolecular C-H Interactions in Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

S. Shanmuga Sundara Raj
, Hoong-Kun Fun
, Ji Wu
, Yu-Peng Tian
, Fu-Xin Xie
, Ze-Huai Shao
, Sheng-Li Li

Biochemistry, Chemistry & Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Ni(C(21)H(15)N(2)S(2))(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacking between the fluorene moieties and extensive C-H.pi interactions.

Original language	American English
Journal	Acta Crystallographica, Section C
Volume	56
State	Published - 2000

Disciplines

Biology

Keywords

Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3
C-H interactions
Intermolecular
Intra-

Cite this

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title = "Intra- and Intermolecular C-H Interactions in Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)",

abstract = " The title compound, [Ni(C(21)H(15)N(2)S(2))(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacking between the fluorene moieties and extensive C-H.pi interactions.",

keywords = "Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3, C-H interactions, Intermolecular, Intra-",

author = "Raj, \{S. Shanmuga Sundara\} and Hoong-Kun Fun and Ji Wu and Yu-Peng Tian and Fu-Xin Xie and Ze-Huai Shao and Sheng-Li Li",

year = "2000",

language = "American English",

volume = "56",

journal = "Acta Crystallographica, Section C",

}

TY - JOUR

T1 - Intra- and Intermolecular C-H Interactions in Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

AU - Raj, S. Shanmuga Sundara

AU - Fun, Hoong-Kun

AU - Wu, Ji

AU - Tian, Yu-Peng

AU - Xie, Fu-Xin

AU - Shao, Ze-Huai

AU - Li, Sheng-Li

PY - 2000

Y1 - 2000

N2 - The title compound, [Ni(C(21)H(15)N(2)S(2))(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacking between the fluorene moieties and extensive C-H.pi interactions.

AB - The title compound, [Ni(C(21)H(15)N(2)S(2))(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacking between the fluorene moieties and extensive C-H.pi interactions.

KW - Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3

KW - C-H interactions

KW - Intermolecular

KW - Intra-

UR - https://journals.iucr.org/c/issues/2000/11/00/sk1413/sk1413.pdf

M3 - Article

VL - 56

JO - Acta Crystallographica, Section C

JF - Acta Crystallographica, Section C

ER -

Intra- and Intermolecular C-H Interactions in Bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

Abstract

Disciplines

Keywords

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