Ionic rectification through the formation of complexes or precipitation in carbon nanotube membranes

Bhavin Patel, Mayur Patel, Matthew Bassett, Shainaz Landge, Xuezhen Haung, Hongrui Jiang, Ji Wu, Shainaz M. Landge

Research output: Contribution to journalArticlepeer-review

Abstract

Carbon nanotube membranes were fabricated using arrays of millimeter-long multiwalled carbon nanotubes (MWCNTs) with an inner diameter of about 8nm through a low-cost cast-polishing method. The fabricated carbon nanotube membranes demonstrated a unique ionic rectification phenomenon through two fundamentally different mechanisms: a) the formation of metal ion complexes and b) the precipitation of insoluble lead molybdate inside the carbon nanotubes. These discoveries could be applied to detecting the presence of toxic metal ions in contaminated water resources through a relatively simple approach.

Original languageEnglish
Pages (from-to)1173-1175
Number of pages3
JournalChemistry Letters
Volume42
Issue number10
DOIs
StatePublished - 2013

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