Itaconic Anhydride as a Green Compatibilizer in Composites Prepared by the Reinforcement of a Tung Oil-Based Thermosetting Resin with Miscanthus, Pine Wood, or Algae Biomass

Julio Antonio Conti Silva, Hannah Walton, Seth Dever, Kamran Kardel, Talita Martins Lacerda, Rafael Lopes Quirino

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Unsaturated vegetable oils with conjugated carbon–carbon double bonds, such as tung oil, can undergo free-radical polymerization, originating alternatives to petroleum-based materials. The introduction of fillers to vegetable oil-based polymer matrices results in composites with improved mechanical properties. In this work, thermosets were synthesized by the free-radical polymerization of a mixture of tung oil, divinylbenzene, and n-butyl methacrylate, and reinforced with bio-based fillers, namely Miscanthus, Pinus taeda (also known as southern pine), and algae (Microspora and Oedogonium) biomass. The effect of filler particle size on the composites’ properties was evaluated. Additionally, to develop a better interaction between the hydrophobic resin and the hydrophilic reinforcements, and improve the mechanical properties of the composites prepared, itaconic anhydride, a bio-based molecule derived from itaconic acid, was added to the resin. Thermogravimetric analysis (TGA) showed that the presence of itaconic anhydride improved the overall thermal stability of the composites. The storage modulus of the composites at room temperature, assessed by dynamic mechanical analysis (DMA), was increased by approximately 32% and 68%, for Miscanthus and southern pine composites, respectively, when itaconic acid was added to the resin. It was also observed that the glass transition temperatures were not significantly affected by the presence of itaconic acid. Scanning electron microscope (SEM) images indicated better matrix-reinforcement adhesion in the presence of itaconic anhydride.

Original languageEnglish
Article number25
JournalCoatings
Volume13
Issue number1
DOIs
StatePublished - Jan 2023

Scopus Subject Areas

  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Keywords

  • algal biomass
  • biocomposites
  • itaconic anhydride
  • lignocellulosic biomass
  • tung oil

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