Abstract
Photoluminescence has been measured from 100 to 300nm epitaxial thin films of MnF 2 prepared on Si(1 1 1) substrates and having α-PbO 2 orthorhombic structural type. The dominant luminescence consists of a broad band peaking around 575nm with a gradual tail extending to longer wavelengths. Weak spectral line features are observed on the short-wavelength side of the main band and are associated with magnon sidebands of Mn 2+ excitons that are perturbed by Mg and Ca impurities. Of note is a blue shift (∼12nm) of these sidebands when compared to their positions in bulk MnF 2. The shift can be associated with different crystal field for Mn 2+ ions in orthorhombic phase.
| Original language | English |
|---|---|
| Pages (from-to) | 207-210 |
| Number of pages | 4 |
| Journal | Journal of Luminescence |
| Volume | 94-95 |
| DOIs | |
| State | Published - Dec 1 2001 |
Scopus Subject Areas
- Biophysics
- Biochemistry
- General Chemistry
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
Keywords
- MnF epitaxial layers
- Photoluminescence