Nonlinear Effects in Chromophore Doped Sol-Gel Photonic Materials

X. D. Sun; X. J. Wang; W. Shan; J. J. Song; M. G. Fan; E. T. Knobbe

doi:10.1007/BF02439397

Nonlinear Effects in Chromophore Doped Sol-Gel Photonic Materials

X. D. Sun, X. J. Wang, W. Shan, J. J. Song, M. G. Fan, E. T. Knobbe

Biochemistry, Chemistry, & Physics

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS), and 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3′-[3H]-naphth[2,1-b][1,4] oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts. Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.

Original language	English
Pages (from-to)	169-181
Number of pages	13
Journal	Journal of Sol-Gel Science and Technology
Volume	9
Issue number	2
DOIs	https://doi.org/10.1007/BF02439397
State	Published - 1997

Keywords

Aluminosilicate gel
Metalloporphyrin
Non-linear absorption
Spirooxazine
Time-resolved spectroscopy

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10.1007/BF02439397

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title = "Nonlinear Effects in Chromophore Doped Sol-Gel Photonic Materials",

abstract = "Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS), and 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3′-[3H]-naphth[2,1-b][1,4] oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts. Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.",

keywords = "Aluminosilicate gel, Metalloporphyrin, Non-linear absorption, Spirooxazine, Time-resolved spectroscopy",

author = "Sun, {X. D.} and Wang, {X. J.} and W. Shan and Song, {J. J.} and Fan, {M. G.} and Knobbe, {E. T.}",

year = "1997",

doi = "10.1007/BF02439397",

language = "English",

volume = "9",

pages = "169--181",

journal = "Journal of Sol-Gel Science and Technology",

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T1 - Nonlinear Effects in Chromophore Doped Sol-Gel Photonic Materials

AU - Sun, X. D.

AU - Wang, X. J.

AU - Shan, W.

AU - Song, J. J.

AU - Fan, M. G.

AU - Knobbe, E. T.

PY - 1997

Y1 - 1997

N2 - Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS), and 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3′-[3H]-naphth[2,1-b][1,4] oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts. Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.

AB - Linear and nonlinear optical effects have been studied in chromophore-doped gel hosts. Tetra-4-sulfonatophenylporphyrinatocopper(II) (CuTPPS), and 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3′-[3H]-naphth[2,1-b][1,4] oxazine] (SP spirooxazine) species were entrapped within porous aluminosilicate hosts. Optical limiting effects and radiative up-conversion behavior in the CuTPPS-doped materials are described, and a six-level model is proposed based on experimental findings. Spirooxazine-containing specimens exhibiting photochromic effects were prepared, and cw and time-resolved spectroscopy methods are used to assess excited state band structures and the nature of guest-host interactions in the resultant gels.

KW - Aluminosilicate gel

KW - Metalloporphyrin

KW - Non-linear absorption

KW - Spirooxazine

KW - Time-resolved spectroscopy

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U2 - 10.1007/BF02439397

DO - 10.1007/BF02439397

M3 - Article

AN - SCOPUS:0031095112

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SP - 169

EP - 181

JO - Journal of Sol-Gel Science and Technology

JF - Journal of Sol-Gel Science and Technology

IS - 2

ER -

Nonlinear Effects in Chromophore Doped Sol-Gel Photonic Materials

Abstract

Keywords

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