Oxidation of 13C-labeled ethyl linoleate monitored and quantitatively analyzed by 13C NMR

Z. O. Oyman; W. Ming; R. van der Linde

doi:10.1016/j.eurpolymj.2005.12.003

Oxidation of ¹³C-labeled ethyl linoleate monitored and quantitatively analyzed by ¹³C NMR

Z. O. Oyman, W. Ming, R. van der Linde

Biochemistry, Chemistry, & Physics

Eindhoven University of Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The oxidation of ¹³C-labeled ethyl linoleate (¹³C-EL), a model compound for alkyd resins, was investigated by ¹³C NMR in the presence of Co(II)-2-ethylhexanoate (Co-EH), Mn(acac)₃ (acac = acetylacetonate), and Mn(acac)₃ in combination with 2,2′-bipyridine (bpy), respectively. The use of ¹³C-EL allows us, in an unprecedented way, to reveal the individual evolution of hydroperoxides (ROOH) and peroxy (ROOR) links by ¹³C NMR and to quantify the oxidation intermediates during the oxidation. Mn(acac)₃ appeared to be less effective in decomposing ROOH than Co-EH and the Mn(acac)₃/bpy combination. Quantitative analyses were attempted for a few major ¹³C peaks.

Original language	English
Pages (from-to)	1342-1348
Number of pages	7
Journal	European Polymer Journal
Volume	42
Issue number	6
DOIs	https://doi.org/10.1016/j.eurpolymj.2005.12.003
State	Published - Jun 2006

Keywords

C NMR
C-labeled ethyl linoleate
Alkyd
Oxidation

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10.1016/j.eurpolymj.2005.12.003

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title = "Oxidation of 13C-labeled ethyl linoleate monitored and quantitatively analyzed by 13C NMR",

abstract = "The oxidation of 13C-labeled ethyl linoleate (13C-EL), a model compound for alkyd resins, was investigated by 13C NMR in the presence of Co(II)-2-ethylhexanoate (Co-EH), Mn(acac)3 (acac = acetylacetonate), and Mn(acac)3 in combination with 2,2′-bipyridine (bpy), respectively. The use of 13C-EL allows us, in an unprecedented way, to reveal the individual evolution of hydroperoxides (ROOH) and peroxy (ROOR) links by 13C NMR and to quantify the oxidation intermediates during the oxidation. Mn(acac)3 appeared to be less effective in decomposing ROOH than Co-EH and the Mn(acac)3/bpy combination. Quantitative analyses were attempted for a few major 13C peaks.",

keywords = "C NMR, C-labeled ethyl linoleate, Alkyd, Oxidation",

author = "Oyman, {Z. O.} and W. Ming and {van der Linde}, R.",

year = "2006",

month = jun,

doi = "10.1016/j.eurpolymj.2005.12.003",

language = "English",

volume = "42",

pages = "1342--1348",

journal = "European Polymer Journal",

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publisher = "Elsevier Ltd",

number = "6",

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TY - JOUR

T1 - Oxidation of 13C-labeled ethyl linoleate monitored and quantitatively analyzed by 13C NMR

AU - Oyman, Z. O.

AU - Ming, W.

AU - van der Linde, R.

PY - 2006/6

Y1 - 2006/6

N2 - The oxidation of 13C-labeled ethyl linoleate (13C-EL), a model compound for alkyd resins, was investigated by 13C NMR in the presence of Co(II)-2-ethylhexanoate (Co-EH), Mn(acac)3 (acac = acetylacetonate), and Mn(acac)3 in combination with 2,2′-bipyridine (bpy), respectively. The use of 13C-EL allows us, in an unprecedented way, to reveal the individual evolution of hydroperoxides (ROOH) and peroxy (ROOR) links by 13C NMR and to quantify the oxidation intermediates during the oxidation. Mn(acac)3 appeared to be less effective in decomposing ROOH than Co-EH and the Mn(acac)3/bpy combination. Quantitative analyses were attempted for a few major 13C peaks.

AB - The oxidation of 13C-labeled ethyl linoleate (13C-EL), a model compound for alkyd resins, was investigated by 13C NMR in the presence of Co(II)-2-ethylhexanoate (Co-EH), Mn(acac)3 (acac = acetylacetonate), and Mn(acac)3 in combination with 2,2′-bipyridine (bpy), respectively. The use of 13C-EL allows us, in an unprecedented way, to reveal the individual evolution of hydroperoxides (ROOH) and peroxy (ROOR) links by 13C NMR and to quantify the oxidation intermediates during the oxidation. Mn(acac)3 appeared to be less effective in decomposing ROOH than Co-EH and the Mn(acac)3/bpy combination. Quantitative analyses were attempted for a few major 13C peaks.

KW - C NMR

KW - C-labeled ethyl linoleate

KW - Alkyd

KW - Oxidation

UR - http://www.scopus.com/inward/record.url?scp=33646172775&partnerID=8YFLogxK

U2 - 10.1016/j.eurpolymj.2005.12.003

DO - 10.1016/j.eurpolymj.2005.12.003

M3 - Article

AN - SCOPUS:33646172775

SN - 0014-3057

VL - 42

SP - 1342

EP - 1348

JO - European Polymer Journal

JF - European Polymer Journal

IS - 6

ER -

Oxidation of ¹³C-labeled ethyl linoleate monitored and quantitatively analyzed by ¹³C NMR

Abstract

Keywords

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