Preparation of Co3O4/Nitrogen-Doped Carbon Composite by in Situ Solvothermal with Ionic Liquid and Its Electrochemical Performance as Lithium-Ion Battery Anode

Mingjun Xiao; Yanshuang Meng; Chaoyu Duan; Qianru Hu; Ruinian Li; Fuliang Zhu; Yue Zhang

doi:10.1007/s11581-018-2831-9

Preparation of Co3O4/Nitrogen-Doped Carbon Composite by in Situ Solvothermal with Ionic Liquid and Its Electrochemical Performance as Lithium-Ion Battery Anode

Mingjun Xiao, Yanshuang Meng, Chaoyu Duan, Qianru Hu, Ruinian Li, Fuliang Zhu, Yue Zhang

Manufacturing Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

In this work, the Co ₃ O ₄ /nitrogen-doped carbon (Co ₃ O ₄ /NDC) composite was prepared by in situ solvothermal method using ionic liquid as carbon and nitrogen sources. The Co ₃ O ₄ /NDC composite was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and electrochemical testing. The HRTEM results show that there is a thin layer of amorphous carbon film on the surface of Co ₃ O ₄ particles, which can improve the conductivity of Co ₃ O ₄ and inhibit the fragmentation of material caused by volume expansion. When the Co ₃ O ₄ /NDC composite is used as the anode material of lithium-ion batteries, the reversible capacity is 1056 mAh g ⁻¹ after 50 cycles at 0.1 C. The superior electrochemical performance can be attributed to the synergistic effect of amorphous carbon film, nitrogen doping, and Co ₃ O ₄ particles.

Original language	American English
Journal	Ionics
Volume	25
DOIs	https://doi.org/10.1007/s11581-018-2831-9
State	Published - Feb 1 2019

Keywords

Co3O4/nitrogen-doped carbon composite
In situ solvothermal method
Ionic liquids
Lithium-ion batteries

DC Disciplines

Manufacturing

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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@article{8b4f5919ea5c439d8f07e3be224a8637,

title = "Preparation of Co3O4/Nitrogen-Doped Carbon Composite by in Situ Solvothermal with Ionic Liquid and Its Electrochemical Performance as Lithium-Ion Battery Anode",

abstract = " In this work, the Co 3 O 4 /nitrogen-doped carbon (Co 3 O 4 /NDC) composite was prepared by in situ solvothermal method using ionic liquid as carbon and nitrogen sources. The Co 3 O 4 /NDC composite was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and electrochemical testing. The HRTEM results show that there is a thin layer of amorphous carbon film on the surface of Co 3 O 4 particles, which can improve the conductivity of Co 3 O 4 and inhibit the fragmentation of material caused by volume expansion. When the Co 3 O 4 /NDC composite is used as the anode material of lithium-ion batteries, the reversible capacity is 1056 mAh g −1 after 50 cycles at 0.1 C. The superior electrochemical performance can be attributed to the synergistic effect of amorphous carbon film, nitrogen doping, and Co 3 O 4 particles.",

keywords = "Co3O4/nitrogen-doped carbon composite, In situ solvothermal method, Ionic liquids, Lithium-ion batteries",

author = "Mingjun Xiao and Yanshuang Meng and Chaoyu Duan and Qianru Hu and Ruinian Li and Fuliang Zhu and Yue Zhang",

note = "Publisher Copyright: {\textcopyright} 2018, Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2019",

month = feb,

day = "1",

doi = "10.1007/s11581-018-2831-9",

language = "American English",

volume = "25",

journal = "Ionics",

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TY - JOUR

T1 - Preparation of Co3O4/Nitrogen-Doped Carbon Composite by in Situ Solvothermal with Ionic Liquid and Its Electrochemical Performance as Lithium-Ion Battery Anode

AU - Xiao, Mingjun

AU - Meng, Yanshuang

AU - Duan, Chaoyu

AU - Hu, Qianru

AU - Li, Ruinian

AU - Zhu, Fuliang

AU - Zhang, Yue

PY - 2019/2/1

Y1 - 2019/2/1

N2 - In this work, the Co 3 O 4 /nitrogen-doped carbon (Co 3 O 4 /NDC) composite was prepared by in situ solvothermal method using ionic liquid as carbon and nitrogen sources. The Co 3 O 4 /NDC composite was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and electrochemical testing. The HRTEM results show that there is a thin layer of amorphous carbon film on the surface of Co 3 O 4 particles, which can improve the conductivity of Co 3 O 4 and inhibit the fragmentation of material caused by volume expansion. When the Co 3 O 4 /NDC composite is used as the anode material of lithium-ion batteries, the reversible capacity is 1056 mAh g −1 after 50 cycles at 0.1 C. The superior electrochemical performance can be attributed to the synergistic effect of amorphous carbon film, nitrogen doping, and Co 3 O 4 particles.

AB - In this work, the Co 3 O 4 /nitrogen-doped carbon (Co 3 O 4 /NDC) composite was prepared by in situ solvothermal method using ionic liquid as carbon and nitrogen sources. The Co 3 O 4 /NDC composite was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and electrochemical testing. The HRTEM results show that there is a thin layer of amorphous carbon film on the surface of Co 3 O 4 particles, which can improve the conductivity of Co 3 O 4 and inhibit the fragmentation of material caused by volume expansion. When the Co 3 O 4 /NDC composite is used as the anode material of lithium-ion batteries, the reversible capacity is 1056 mAh g −1 after 50 cycles at 0.1 C. The superior electrochemical performance can be attributed to the synergistic effect of amorphous carbon film, nitrogen doping, and Co 3 O 4 particles.

KW - Co3O4/nitrogen-doped carbon composite

KW - In situ solvothermal method

KW - Ionic liquids

KW - Lithium-ion batteries

UR - https://digitalcommons.georgiasouthern.edu/manufact-eng-facpubs/83

U2 - 10.1007/s11581-018-2831-9

DO - 10.1007/s11581-018-2831-9

M3 - Article

SN - 0947-7047

VL - 25

JO - Ionics

JF - Ionics

ER -

Preparation of Co3O4/Nitrogen-Doped Carbon Composite by in Situ Solvothermal with Ionic Liquid and Its Electrochemical Performance as Lithium-Ion Battery Anode

Abstract

Keywords

DC Disciplines

UN SDGs

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