Pressure-induced dark-to-bright transition in Lu2O3:Ce3+

Yongrong Shen; Delena B. Gatch; Ulises R. Rodróguez Mendoza; Garry Cunningham; Richard S. Meltzer; William M. Yen; Kevin L. Bray

doi:10.1103/PhysRevB.65.212103

Pressure-induced dark-to-bright transition in Lu₂O₃:Ce³⁺

Yongrong Shen
, Delena B. Gatch
, Ulises R. Rodróguez Mendoza
, Garry Cunningham
, Richard S. Meltzer
, William M. Yen
, Kevin L. Bray

Biochemistry, Chemistry & Physics

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Application of pressure to the nonemitting system Lu₂O₃:Ce³⁺ leads to the generation of luminescence in the visible. The luminescence is assigned to the 5d→4f transition of Ce³⁺, and is attributed to a pressure-induced electronic-crossover of the excited 5d state of Ce³⁺ and the conduction-band edge of Lu₂O³. The results yield insight into the emission efficiency of 5d→4f transitions, and provide a foundation for advancing new phosphors and tunable laser materials in the visible and ultraviolet based on the broad 5d→4f emission of lanthanides.

Original language	English
Article number	212103
Pages (from-to)	2121031-2121034
Number of pages	4
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	65
Issue number	21
DOIs	https://doi.org/10.1103/PhysRevB.65.212103
State	Published - Jun 1 2002

Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1103/PhysRevB.65.212103

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@article{c1358952748241b98213c374d5670951,

title = "Pressure-induced dark-to-bright transition in Lu2O3:Ce3+",

abstract = "Application of pressure to the nonemitting system Lu2O3:Ce3+ leads to the generation of luminescence in the visible. The luminescence is assigned to the 5d→4f transition of Ce3+, and is attributed to a pressure-induced electronic-crossover of the excited 5d state of Ce3+ and the conduction-band edge of Lu2O3. The results yield insight into the emission efficiency of 5d→4f transitions, and provide a foundation for advancing new phosphors and tunable laser materials in the visible and ultraviolet based on the broad 5d→4f emission of lanthanides.",

author = "Yongrong Shen and Gatch, \{Delena B.\} and \{Rodr{\'o}guez Mendoza\}, \{Ulises R.\} and Garry Cunningham and Meltzer, \{Richard S.\} and Yen, \{William M.\} and Bray, \{Kevin L.\}",

year = "2002",

month = jun,

day = "1",

doi = "10.1103/PhysRevB.65.212103",

language = "English",

volume = "65",

pages = "2121031--2121034",

journal = "Physical Review B - Condensed Matter and Materials Physics",

issn = "0163-1829",

publisher = "American Physical Society",

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}

TY - JOUR

T1 - Pressure-induced dark-to-bright transition in Lu2O3:Ce3+

AU - Shen, Yongrong

AU - Gatch, Delena B.

AU - Rodróguez Mendoza, Ulises R.

AU - Cunningham, Garry

AU - Meltzer, Richard S.

AU - Yen, William M.

AU - Bray, Kevin L.

PY - 2002/6/1

Y1 - 2002/6/1

N2 - Application of pressure to the nonemitting system Lu2O3:Ce3+ leads to the generation of luminescence in the visible. The luminescence is assigned to the 5d→4f transition of Ce3+, and is attributed to a pressure-induced electronic-crossover of the excited 5d state of Ce3+ and the conduction-band edge of Lu2O3. The results yield insight into the emission efficiency of 5d→4f transitions, and provide a foundation for advancing new phosphors and tunable laser materials in the visible and ultraviolet based on the broad 5d→4f emission of lanthanides.

AB - Application of pressure to the nonemitting system Lu2O3:Ce3+ leads to the generation of luminescence in the visible. The luminescence is assigned to the 5d→4f transition of Ce3+, and is attributed to a pressure-induced electronic-crossover of the excited 5d state of Ce3+ and the conduction-band edge of Lu2O3. The results yield insight into the emission efficiency of 5d→4f transitions, and provide a foundation for advancing new phosphors and tunable laser materials in the visible and ultraviolet based on the broad 5d→4f emission of lanthanides.

UR - https://www.scopus.com/pages/publications/0036612207

U2 - 10.1103/PhysRevB.65.212103

DO - 10.1103/PhysRevB.65.212103

M3 - Article

SN - 0163-1829

VL - 65

SP - 2121031

EP - 2121034

JO - Physical Review B - Condensed Matter and Materials Physics

JF - Physical Review B - Condensed Matter and Materials Physics

IS - 21

M1 - 212103

ER -

Pressure-induced dark-to-bright transition in Lu₂O₃:Ce³⁺

Abstract

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