Pyrolysis Mechanism of Ionic Liquid Under Microwave Irradiation and the Formation of N-Doped Carbon

Yanshuang Meng; Lei Wang; Yue Zhang; Fuliang Zhu; Dajian Wang

doi:10.1166/jnn.2018.14242

Pyrolysis Mechanism of Ionic Liquid Under Microwave Irradiation and the Formation of N-Doped Carbon

Yanshuang Meng, Lei Wang, Yue Zhang, Fuliang Zhu, Dajian Wang

Manufacturing Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The pyrolysis mechanism of the ionic liquid [BMIm]N(CN) ₂ under microwave irradiation was discussed for the first time. The trimerization of the anion N(CN) ⁻ ₂ and the formation of a framework were firstly caused by the microwave irradiation. And then the carbonization of the framework occurred when the temperature reached 330 °C. The pyrolysis product was graphitic nitrogendoped carbon and mainly originated from the anion N(CN) ⁻ ₂ . The nitrogen content and graphitization degree of the nitrogen-doped carbon was relied on the pyrolysis temperature.

Original language	American English
Journal	Journal of Nanoscience and Nanotechnology
Volume	18
DOIs	https://doi.org/10.1166/jnn.2018.14242
State	Published - Mar 1 2018

Keywords

Formation
Ionic liquid
Microwave irradiation
N-doped carbon
Pyrolysis mechanism

DC Disciplines

Engineering

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https://doi.org/10.1166/jnn.2018.14242

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title = "Pyrolysis Mechanism of Ionic Liquid Under Microwave Irradiation and the Formation of N-Doped Carbon",

abstract = " The pyrolysis mechanism of the ionic liquid [BMIm]N(CN) 2 under microwave irradiation was discussed for the first time. The trimerization of the anion N(CN) − 2 and the formation of a framework were firstly caused by the microwave irradiation. And then the carbonization of the framework occurred when the temperature reached 330 °C. The pyrolysis product was graphitic nitrogendoped carbon and mainly originated from the anion N(CN) − 2 . The nitrogen content and graphitization degree of the nitrogen-doped carbon was relied on the pyrolysis temperature.",

keywords = "Formation, Ionic liquid, Microwave irradiation, N-doped carbon, Pyrolysis mechanism",

author = "Yanshuang Meng and Lei Wang and Yue Zhang and Fuliang Zhu and Dajian Wang",

year = "2018",

month = mar,

day = "1",

doi = "10.1166/jnn.2018.14242",

language = "American English",

volume = "18",

journal = "Journal of Nanoscience and Nanotechnology",

publisher = "American Scientific Publishers",

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TY - JOUR

T1 - Pyrolysis Mechanism of Ionic Liquid Under Microwave Irradiation and the Formation of N-Doped Carbon

AU - Meng, Yanshuang

AU - Wang, Lei

AU - Zhang, Yue

AU - Zhu, Fuliang

AU - Wang, Dajian

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The pyrolysis mechanism of the ionic liquid [BMIm]N(CN) 2 under microwave irradiation was discussed for the first time. The trimerization of the anion N(CN) − 2 and the formation of a framework were firstly caused by the microwave irradiation. And then the carbonization of the framework occurred when the temperature reached 330 °C. The pyrolysis product was graphitic nitrogendoped carbon and mainly originated from the anion N(CN) − 2 . The nitrogen content and graphitization degree of the nitrogen-doped carbon was relied on the pyrolysis temperature.

AB - The pyrolysis mechanism of the ionic liquid [BMIm]N(CN) 2 under microwave irradiation was discussed for the first time. The trimerization of the anion N(CN) − 2 and the formation of a framework were firstly caused by the microwave irradiation. And then the carbonization of the framework occurred when the temperature reached 330 °C. The pyrolysis product was graphitic nitrogendoped carbon and mainly originated from the anion N(CN) − 2 . The nitrogen content and graphitization degree of the nitrogen-doped carbon was relied on the pyrolysis temperature.

KW - Formation

KW - Ionic liquid

KW - Microwave irradiation

KW - N-doped carbon

KW - Pyrolysis mechanism

UR - https://digitalcommons.georgiasouthern.edu/manufact-eng-facpubs/27

UR - https://doi.org/10.1166/jnn.2018.14242

U2 - 10.1166/jnn.2018.14242

DO - 10.1166/jnn.2018.14242

M3 - Article

VL - 18

JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

ER -

Pyrolysis Mechanism of Ionic Liquid Under Microwave Irradiation and the Formation of N-Doped Carbon

Abstract

Keywords

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