Sand composites prepared with a tung oil-based, crosslinked resin and its preliminary trials in binder jetting

In this work, a tung oil-based thermosetting resin was synthesized via free radical polymerization and reinforced with thirteen different types of sand. The viability of this process inspired the adaptation of the resin for its use as a binder material in binder jetting, an additive manufacturing process. Firstly, it was shown that the resin could have its initial viscosity (∼0.33 cP) increased upon heating to attain values compatible to existing printing systems. The curing kinetics of the resin was assessed via dielectric analysis (DEA), combining the utilization of heat and ultraviolet (UV) light, showing that a resin with a viscosity of 10 cP can be fully cured after 250 min at 90 °C, or 300 min at 75 °C, both under a 365 nm light exposure. Preliminary binder-jet tests successfully provided a solid object, which was post-cured, resulting in a hard specimen. The results presented herein suggest that the tung oil-based resin in question is a suitable bio-based binder for binder-jet 3D-printing applications. The novelty of the work reported lies in the conversion of an already established and effective bio-based thermosetting resin into a versatile photocurable binder that can be irrestrictively used with unsorted sands of different composition, making this technology broadly applicable to different isolated regions, using local resources available. The technology presented herein is potentially transformative and impactful, as binder jetting is typically associated to extremely well-sorted particles.