TY - JOUR
T1 - Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review
AU - Su, Xin
AU - Wu, Qingliu
AU - Li, Juchuan
AU - Xiao, Xingcheng
AU - Lott, Amber
AU - Lu, Wenquan
AU - Sheldon, Brian W.
AU - Wu, Ji
PY - 2014/1/7
Y1 - 2014/1/7
N2 - There are growing concerns over the environmental, climate, and health impacts caused by using non-renewable fossil fuels. The utilization of green energy, including solar and wind power, is believed to be one of the most promising alternatives to support more sustainable economic growth. In this regard, lithium-ion batteries (LIBs) can play a critically important role. To further increase the energy and power densities of LIBs, silicon anodes have been intensively explored due to their high capacity, low operation potential, environmental friendliness, and high abundance. The main challenges for the practical implementation of silicon anodes, however, are the huge volume variation during lithiation and delithiation processes and the unstable solid-electrolyte interphase (SEI) films. Recently, significant breakthroughs have been achieved utilizing advanced nanotechnologies in terms of increasing cycle life and enhancing charging rate performance due partially to the excellent mechanical properties of nanomaterials, high surface area, and fast lithium and electron transportation. Here, the most recent advance in the applications of 0D (nanoparticles), 1D (nanowires and nanotubes), and 2D (thin film) silicon nanomaterials in LIBs are summarized. The synthetic routes and electrochemical performance of these Si nanomaterials, and the underlying reaction mechanisms are systematically described. The most recent advance in the applications of 0D (nanoparticles), 1D (nanowires and nanotubes), and 2D (thin film) silicon nanomaterials in lithium ion batteries (LIBs) are summarized. The synthetic routes, electrochemical performance, and underlying reaction mechanisms of these nanomaterials are described and the advantages and limitations using nanostructured silicon in LIBs are also discussed.
AB - There are growing concerns over the environmental, climate, and health impacts caused by using non-renewable fossil fuels. The utilization of green energy, including solar and wind power, is believed to be one of the most promising alternatives to support more sustainable economic growth. In this regard, lithium-ion batteries (LIBs) can play a critically important role. To further increase the energy and power densities of LIBs, silicon anodes have been intensively explored due to their high capacity, low operation potential, environmental friendliness, and high abundance. The main challenges for the practical implementation of silicon anodes, however, are the huge volume variation during lithiation and delithiation processes and the unstable solid-electrolyte interphase (SEI) films. Recently, significant breakthroughs have been achieved utilizing advanced nanotechnologies in terms of increasing cycle life and enhancing charging rate performance due partially to the excellent mechanical properties of nanomaterials, high surface area, and fast lithium and electron transportation. Here, the most recent advance in the applications of 0D (nanoparticles), 1D (nanowires and nanotubes), and 2D (thin film) silicon nanomaterials in LIBs are summarized. The synthetic routes and electrochemical performance of these Si nanomaterials, and the underlying reaction mechanisms are systematically described. The most recent advance in the applications of 0D (nanoparticles), 1D (nanowires and nanotubes), and 2D (thin film) silicon nanomaterials in lithium ion batteries (LIBs) are summarized. The synthetic routes, electrochemical performance, and underlying reaction mechanisms of these nanomaterials are described and the advantages and limitations using nanostructured silicon in LIBs are also discussed.
KW - anodes
KW - capacity
KW - lithium-ion batteries
KW - nanomaterials
KW - silicon
UR - https://digitalcommons.georgiasouthern.edu/chem-facpubs/50
UR - https://doi.org/10.1002/aenm.201300882
U2 - 10.1002/aenm.201300882
DO - 10.1002/aenm.201300882
M3 - Article
SN - 1614-6832
VL - 4
JO - Advanced Energy Materials
JF - Advanced Energy Materials
ER -