Solventless liquid oligoesters analyzed by MALDI-ToF-MS

Robin X.E. Willemse; Weihua Ming; Alex M. Van Herk

doi:10.1021/ma0501996

Solventless liquid oligoesters analyzed by MALDI-ToF-MS

Robin X.E. Willemse
, Weihua Ming
, Alex M. Van Herk

Biochemistry, Chemistry & Physics

Eindhoven University of Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

MALDI-ToF-MS mass spectra of copolymers contain a lot of information on both chain-length distribution (CLD) and chemical composition distribution (CCD). In this paper, two random solventless liquid oligoesters were synthesized by an esterification of 1,4-butanediol with adipic acid and isophthalic acid or glutaric acid, respectively. The thus obtained oligoesters contain two different repeat units and may therefore be regarded as a copolymer. A copolymer fingerprint analysis has been used to study the microstructure of the copolymers for which it was observed that the copolymers can be described very well using Bernoullian chain statistics.

Original language	English
Pages (from-to)	6876-6881
Number of pages	6
Journal	Macromolecules
Volume	38
Issue number	16
DOIs	https://doi.org/10.1021/ma0501996
State	Published - Aug 9 2005

Scopus Subject Areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma0501996

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title = "Solventless liquid oligoesters analyzed by MALDI-ToF-MS",

abstract = "MALDI-ToF-MS mass spectra of copolymers contain a lot of information on both chain-length distribution (CLD) and chemical composition distribution (CCD). In this paper, two random solventless liquid oligoesters were synthesized by an esterification of 1,4-butanediol with adipic acid and isophthalic acid or glutaric acid, respectively. The thus obtained oligoesters contain two different repeat units and may therefore be regarded as a copolymer. A copolymer fingerprint analysis has been used to study the microstructure of the copolymers for which it was observed that the copolymers can be described very well using Bernoullian chain statistics.",

author = "Willemse, \{Robin X.E.\} and Weihua Ming and \{Van Herk\}, \{Alex M.\}",

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AU - Willemse, Robin X.E.

AU - Ming, Weihua

AU - Van Herk, Alex M.

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Y1 - 2005/8/9

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AB - MALDI-ToF-MS mass spectra of copolymers contain a lot of information on both chain-length distribution (CLD) and chemical composition distribution (CCD). In this paper, two random solventless liquid oligoesters were synthesized by an esterification of 1,4-butanediol with adipic acid and isophthalic acid or glutaric acid, respectively. The thus obtained oligoesters contain two different repeat units and may therefore be regarded as a copolymer. A copolymer fingerprint analysis has been used to study the microstructure of the copolymers for which it was observed that the copolymers can be described very well using Bernoullian chain statistics.

UR - https://www.scopus.com/pages/publications/23844540344

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DO - 10.1021/ma0501996

M3 - Article

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JO - Macromolecules

JF - Macromolecules

IS - 16

ER -

Solventless liquid oligoesters analyzed by MALDI-ToF-MS

Abstract

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