Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol

Brooke Harris; Nicholas Shumate; Kiana Moncur; Glory Onajobi; Michael Reagan; Clifford W. Padgett; Eric T. Drew; Z. John Zhang; Arpita Saha

doi:10.1016/j.inoche.2020.108226

Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol

Brooke Harris
, Nicholas Shumate
, Kiana Moncur
, Glory Onajobi
, Michael Reagan
, Clifford W. Padgett
, Eric T. Drew
, Z. John Zhang
, Arpita Saha

Biochemistry, Chemistry & Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The syntheses, crystal structures and magnetochemical characterization are reported for two novel high-valent manganese complexes, (NMe₄)₂(Mn₃O(PNH)₃(PN)₃) (1) and, (NH₄)[Mn₇(PN)₆(PNH)₂(MeO)₂(O)₂(CMe₃CH₂CO₂)₂] (2) incorporating the anion of 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol. Complexes were characterized by elemental and thermogravimetric analyses, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. Variable temperature, solid-state direct current (dc) magnetization studies were carried out on both the complexes 1 and 2 in the 5.0–315 K range, and they established that both complexes to have ground state spin values of S = 5.

Original language	English
Article number	108226
Journal	Inorganic Chemistry Communications
Volume	121
DOIs	https://doi.org/10.1016/j.inoche.2020.108226
State	Published - Nov 2020

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Coordination chemistry
Molecular magnetism
Polynuclear Mn complexes

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10.1016/j.inoche.2020.108226

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Harris, B., Shumate, N., Moncur, K., Onajobi, G., Reagan, M., Padgett, C. W., Drew, E. T., Zhang, Z. J., & Saha, A. (2020). Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol. Inorganic Chemistry Communications, 121, Article 108226. https://doi.org/10.1016/j.inoche.2020.108226

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title = "Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol",

abstract = "The syntheses, crystal structures and magnetochemical characterization are reported for two novel high-valent manganese complexes, (NMe4)2(Mn3O(PNH)3(PN)3) (1) and, (NH4)[Mn7(PN)6(PNH)2(MeO)2(O)2(CMe3CH2CO2)2] (2) incorporating the anion of 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol. Complexes were characterized by elemental and thermogravimetric analyses, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. Variable temperature, solid-state direct current (dc) magnetization studies were carried out on both the complexes 1 and 2 in the 5.0–315 K range, and they established that both complexes to have ground state spin values of S = 5.",

keywords = "Coordination chemistry, Molecular magnetism, Polynuclear Mn complexes",

author = "Brooke Harris and Nicholas Shumate and Kiana Moncur and Glory Onajobi and Michael Reagan and Padgett, \{Clifford W.\} and Drew, \{Eric T.\} and Zhang, \{Z. John\} and Arpita Saha",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = nov,

doi = "10.1016/j.inoche.2020.108226",

language = "English",

volume = "121",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol

AU - Harris, Brooke

AU - Shumate, Nicholas

AU - Moncur, Kiana

AU - Onajobi, Glory

AU - Reagan, Michael

AU - Padgett, Clifford W.

AU - Drew, Eric T.

AU - Zhang, Z. John

AU - Saha, Arpita

PY - 2020/11

Y1 - 2020/11

N2 - The syntheses, crystal structures and magnetochemical characterization are reported for two novel high-valent manganese complexes, (NMe4)2(Mn3O(PNH)3(PN)3) (1) and, (NH4)[Mn7(PN)6(PNH)2(MeO)2(O)2(CMe3CH2CO2)2] (2) incorporating the anion of 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol. Complexes were characterized by elemental and thermogravimetric analyses, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. Variable temperature, solid-state direct current (dc) magnetization studies were carried out on both the complexes 1 and 2 in the 5.0–315 K range, and they established that both complexes to have ground state spin values of S = 5.

AB - The syntheses, crystal structures and magnetochemical characterization are reported for two novel high-valent manganese complexes, (NMe4)2(Mn3O(PNH)3(PN)3) (1) and, (NH4)[Mn7(PN)6(PNH)2(MeO)2(O)2(CMe3CH2CO2)2] (2) incorporating the anion of 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol. Complexes were characterized by elemental and thermogravimetric analyses, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. Variable temperature, solid-state direct current (dc) magnetization studies were carried out on both the complexes 1 and 2 in the 5.0–315 K range, and they established that both complexes to have ground state spin values of S = 5.

KW - Coordination chemistry

KW - Molecular magnetism

KW - Polynuclear Mn complexes

UR - https://www.scopus.com/pages/publications/85090912317

U2 - 10.1016/j.inoche.2020.108226

DO - 10.1016/j.inoche.2020.108226

M3 - Article

AN - SCOPUS:85090912317

SN - 1387-7003

VL - 121

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 108226

ER -

Synthesis, structural variation, and magnetic properties of two polynuclear Mn-based complexes derived from 4,5-Bis(hydroxymethyl)-2-methylpyridin-3-ol

Abstract

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Keywords

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