Temperature dependence of structural and luminescent properties of Tb 3+ doped YPO4

Weihua Di; Xiaojun Wang; Baojiu Chen; Xiaoxia Zhao; Guozhong Ren; Qingyu Meng; Yanmin Yang; Huasheng Lai; L. Ü Shaozhe

doi:10.1117/12.667380

Temperature dependence of structural and luminescent properties of Tb ³⁺ doped YPO₄

Weihua Di, Xiaojun Wang, Baojiu Chen, Xiaoxia Zhao, Guozhong Ren, Qingyu Meng, Yanmin Yang, Huasheng Lai, L. Ü Shaozhe

Biochemistry, Chemistry, & Physics

CAS - Changchun Institute of Optics Fine Mechanics and Physics

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

The solution precipitation is used to synthesize the Tb doped yttrium phosphates. The as-synthesized is the monoclinic phased YPO ₄·2H₂O with churchite-type structure, which is transformed to the tetragonal phased YPO₄ with xenotime-rype structure as the temperature approaches 200°C during the thermal treatment process. This phase transformation process can not be observed in some routes that need a higher synthetic temperature, in which, only a high-temperature phase is obtained. The luminescent efficiency dependence on the heat-treatment temperature is investigated. The luminescent efficiency presents a two-step increase respectively around 300 and 700°C. Results indicate that the significant increase of luminescent efficiency at 300°C is not related to the phase structure transformation, but to the decrease of OH^- ions content, and that the significant increase of luminescent efficiency at 700°C is related to the increase of crystallinity, which may increase the absorption to VUV light.

Original language	English
Article number	60300M
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	6030
DOIs	https://doi.org/10.1117/12.667380
State	Published - 2006
Event	ICO20: Display Devices and Systems - Changchun, China Duration: Aug 21 2005 → Aug 26 2005

Keywords

Luminescence
Oh group
Plasma display panel
Structure transformation
Tb
Vacuum ultraviolet

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@article{0b6cb1ff21904c8ba43f21083f7e4806,

title = "Temperature dependence of structural and luminescent properties of Tb 3+ doped YPO4",

abstract = "The solution precipitation is used to synthesize the Tb doped yttrium phosphates. The as-synthesized is the monoclinic phased YPO 4·2H2O with churchite-type structure, which is transformed to the tetragonal phased YPO4 with xenotime-rype structure as the temperature approaches 200°C during the thermal treatment process. This phase transformation process can not be observed in some routes that need a higher synthetic temperature, in which, only a high-temperature phase is obtained. The luminescent efficiency dependence on the heat-treatment temperature is investigated. The luminescent efficiency presents a two-step increase respectively around 300 and 700°C. Results indicate that the significant increase of luminescent efficiency at 300°C is not related to the phase structure transformation, but to the decrease of OH- ions content, and that the significant increase of luminescent efficiency at 700°C is related to the increase of crystallinity, which may increase the absorption to VUV light.",

keywords = "Luminescence, Oh group, Plasma display panel, Structure transformation, Tb, Vacuum ultraviolet",

author = "Weihua Di and Xiaojun Wang and Baojiu Chen and Xiaoxia Zhao and Guozhong Ren and Qingyu Meng and Yanmin Yang and Huasheng Lai and Shaozhe, {L. {\"U}}",

year = "2006",

doi = "10.1117/12.667380",

language = "English",

volume = "6030",

journal = "Proceedings of SPIE - The International Society for Optical Engineering",

issn = "0277-786X",

publisher = "SPIE",

note = "ICO20: Display Devices and Systems ; Conference date: 21-08-2005 Through 26-08-2005",

}

TY - JOUR

T1 - Temperature dependence of structural and luminescent properties of Tb 3+ doped YPO4

AU - Di, Weihua

AU - Wang, Xiaojun

AU - Chen, Baojiu

AU - Zhao, Xiaoxia

AU - Ren, Guozhong

AU - Meng, Qingyu

AU - Yang, Yanmin

AU - Lai, Huasheng

AU - Shaozhe, L. Ü

PY - 2006

Y1 - 2006

N2 - The solution precipitation is used to synthesize the Tb doped yttrium phosphates. The as-synthesized is the monoclinic phased YPO 4·2H2O with churchite-type structure, which is transformed to the tetragonal phased YPO4 with xenotime-rype structure as the temperature approaches 200°C during the thermal treatment process. This phase transformation process can not be observed in some routes that need a higher synthetic temperature, in which, only a high-temperature phase is obtained. The luminescent efficiency dependence on the heat-treatment temperature is investigated. The luminescent efficiency presents a two-step increase respectively around 300 and 700°C. Results indicate that the significant increase of luminescent efficiency at 300°C is not related to the phase structure transformation, but to the decrease of OH- ions content, and that the significant increase of luminescent efficiency at 700°C is related to the increase of crystallinity, which may increase the absorption to VUV light.

AB - The solution precipitation is used to synthesize the Tb doped yttrium phosphates. The as-synthesized is the monoclinic phased YPO 4·2H2O with churchite-type structure, which is transformed to the tetragonal phased YPO4 with xenotime-rype structure as the temperature approaches 200°C during the thermal treatment process. This phase transformation process can not be observed in some routes that need a higher synthetic temperature, in which, only a high-temperature phase is obtained. The luminescent efficiency dependence on the heat-treatment temperature is investigated. The luminescent efficiency presents a two-step increase respectively around 300 and 700°C. Results indicate that the significant increase of luminescent efficiency at 300°C is not related to the phase structure transformation, but to the decrease of OH- ions content, and that the significant increase of luminescent efficiency at 700°C is related to the increase of crystallinity, which may increase the absorption to VUV light.

KW - Luminescence

KW - Oh group

KW - Plasma display panel

KW - Structure transformation

KW - Tb

KW - Vacuum ultraviolet

UR - http://www.scopus.com/inward/record.url?scp=33645237461&partnerID=8YFLogxK

U2 - 10.1117/12.667380

DO - 10.1117/12.667380

M3 - Conference article

AN - SCOPUS:33645237461

SN - 0277-786X

VL - 6030

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

M1 - 60300M

T2 - ICO20: Display Devices and Systems

Y2 - 21 August 2005 through 26 August 2005

ER -

Temperature dependence of structural and luminescent properties of Tb ³⁺ doped YPO₄

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Keywords

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