The synthesis of 1-(4-triethoxysilyl)phenyl-4,4,4-trifluoro-1,3- butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials

Christopher J. Peeples; Raghu Ram Earni; John C. DiCesare

doi:10.3390/molecules13102601

The synthesis of 1-(4-triethoxysilyl)phenyl-4,4,4-trifluoro-1,3- butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials

Christopher J. Peeples, Raghu Ram Earni, John C. DiCesare

Biochemistry, Chemistry & Physics

University of Tulsa

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Abstract

The title compound, 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3- butanedione, was synthesized in a three-step sequence starting from 2-(4-bromophenyl)propene. Containing both a trialkoxysilyl and a substituted 1,3-butanedione functional grouping within its structure, this new silane is a viable starting material for the preparation of functionalized sol-gel materials.

Original language	English
Pages (from-to)	2601-2607
Number of pages	7
Journal	Molecules
Volume	13
Issue number	10
DOIs	https://doi.org/10.3390/molecules13102601
State	Published - Oct 2008

Scopus Subject Areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

Keywords

4,4,4-Trifluoro-1-phenyl-1,3-butanedione (4-TPB)
Molecular imprinting
Sol-gel
Trialkoxysilane

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10.3390/molecules13102601

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title = "The synthesis of 1-(4-triethoxysilyl)phenyl-4,4,4-trifluoro-1,3- butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials",

abstract = "The title compound, 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3- butanedione, was synthesized in a three-step sequence starting from 2-(4-bromophenyl)propene. Containing both a trialkoxysilyl and a substituted 1,3-butanedione functional grouping within its structure, this new silane is a viable starting material for the preparation of functionalized sol-gel materials.",

keywords = "4,4,4-Trifluoro-1-phenyl-1,3-butanedione (4-TPB), Molecular imprinting, Sol-gel, Trialkoxysilane",

author = "Peeples, \{Christopher J.\} and Earni, \{Raghu Ram\} and DiCesare, \{John C.\}",

note = "Christopher J. Peeples, Raghu R. Earni, and John C. DiCesare. {"}The Synthesis of 1-(4-(Triethoxysilyl)Phenyl)-4,4,4-Trifluoro-1,3-Butanedione, A Novel Trialkoxysilane Monomer For The Preparation Of Functionalized Sol-Gel Matrix Materials{"} Molecules 13.10 (2008): 2601-2607. doi:10.3390/molecules13102601 source:http://www.mdpi.com/journal/molecules Available at: http://works.bepress.com/john\_dicesare/4",

year = "2008",

month = oct,

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T1 - The synthesis of 1-(4-triethoxysilyl)phenyl-4,4,4-trifluoro-1,3- butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials

AU - Peeples, Christopher J.

AU - Earni, Raghu Ram

AU - DiCesare, John C.

N1 - Christopher J. Peeples, Raghu R. Earni, and John C. DiCesare. "The Synthesis of 1-(4-(Triethoxysilyl)Phenyl)-4,4,4-Trifluoro-1,3-Butanedione, A Novel Trialkoxysilane Monomer For The Preparation Of Functionalized Sol-Gel Matrix Materials" Molecules 13.10 (2008): 2601-2607. doi:10.3390/molecules13102601 source:http://www.mdpi.com/journal/molecules Available at: http://works.bepress.com/john_dicesare/4

PY - 2008/10

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N2 - The title compound, 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3- butanedione, was synthesized in a three-step sequence starting from 2-(4-bromophenyl)propene. Containing both a trialkoxysilyl and a substituted 1,3-butanedione functional grouping within its structure, this new silane is a viable starting material for the preparation of functionalized sol-gel materials.

AB - The title compound, 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3- butanedione, was synthesized in a three-step sequence starting from 2-(4-bromophenyl)propene. Containing both a trialkoxysilyl and a substituted 1,3-butanedione functional grouping within its structure, this new silane is a viable starting material for the preparation of functionalized sol-gel materials.

KW - 4,4,4-Trifluoro-1-phenyl-1,3-butanedione (4-TPB)

KW - Molecular imprinting

KW - Sol-gel

KW - Trialkoxysilane

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U2 - 10.3390/molecules13102601

DO - 10.3390/molecules13102601

M3 - Article

SN - 1420-3049

VL - 13

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JO - Molecules

JF - Molecules

IS - 10

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The synthesis of 1-(4-triethoxysilyl)phenyl-4,4,4-trifluoro-1,3- butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials

Abstract

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